Second-Generation Biofuels Market Size & Share, by Feedstock (Simple Lignocellulose, Complex Lignocellulose, Syngas, Algae), Application (Transportation, Power Generation), Type (Cellulosic Ethanol, Biodiesel, Bio Butanol, Bio DME), Process (Biochemical Process, Thermochemical Process) - Global Supply & Demand Analysis, Growth Forecasts, Statistics Report 2025-2037

  • Report ID: 4879
  • Published Date: Apr 08, 2025
  • Report Format: PDF, PPT

Global Second-Generation Biofuels Market Size, Forecast, and Trend Highlights Over 2025-2037

Second-Generation Biofuels Market size was over USD 11.52 billion in 2024 and is expected to exceed USD 239.72 billion by the end of 2037, witnessing over 26.3% CAGR during the forecast period i.e., between 2025-2037. In 2025, the industry size of second-generation biofuels is estimated at USD 16.88 billion.

Bioethanol is considered an excellent fossil fuel alternative and caters to the overall rise in energy demand. Presently, research is focused on streamlining sustainable and affordable feedstock supply. Attention has shifted to lignocellulosic waste as a potential feedstock for bioethanol, specifically in developing countries. Over the past few decades, second-generation bioethanol manufacturing from non-food lignocellulosic biomass including organic residues has gained enormous traction owing to its abundance, low cost, and renewability. It aligns with zero waste plans and circular economy strategies, allowing the world economy to decouple from the petrochemical industry.

Total cellulosic ethanol production in Brazil was about 55 million liters in 2022, with an increase of 15 million liters when compared to the previous year. Whereas, in the EU, there are handful plants in Finland, generating 10 million liters per year (MLY) from sawdust, Italy (28 MLY using biomass), Austria (30 MLY from wood sugar), Romania (65 MLY from wheat straw), and Bulgaria (50 MLY using corn stover) as of 2022.  The total capacity in the EU reached 183 MLY in 2022 as per a December 2022 report by the NCBI.  

Technological and R&D advancements have led to the adoption of raw material preparatory treatments with organosol, alkali, sodium hydroxide, acid, ionic liquid, high-frequency heating, sharp steam, lime, and ammonia. Among these, the most promising is organosol preparation and autohydrolysis. They improve the sugar yield, minimize the volume of insoluble lignin, and increase easily fermentable cellulose content. Furthermore, sludge thermobaric hydrolysis is estimated to surge the product output by twofold.

Millet Switchgrass Biomass Composition with Autohydrolysis

Components

Original Biomass, %

Biomass after autohyrolysis, %

Cellulose

46.7±0.5

53.9±0.5

Hemicellulose

23.0±1.0

10.6±1.0

Soluble substances

7.7±0.5

11.5±0.5

Lignin

13.8±0.2

14.7±0.2

Resins and fats

2.0±10

2.0±10

Ash

5.4±0.5

5.4±0.5

Others

1.4±0.2

1.9±0.2

Total

100.0

100.0

Sludge Composition using Autohydrolysis

Components

Original composition, %

Composition after autohyrolysis, %

Cellulose

34.0±0.5

37.0±0.5

Hemicellulose

3.7±1.0

1.5±1.0

Soluble substances

3.2±0.5

6.9±0.5

Lignin

8.5±0.2

3.5±0.2

Resins and fats

2.3±10

2.3±10

Ash

47.8±0.5

48.0±0.5

Others

0.5±0.2

0.8±0.2

Total

100.0

100.0

Source: The Open Agriculture Journal

Husk and straw are the primary rice wastes and have gained widespread adoption as a sustainable energy source due to their high hemicellulose and cellulose compositions. Globally, roughly 120 million tons of rice husks are generated as waste each year. One primary application of rice husk is biofuel production. As per Research Nester estimates, the biofuels market size is projected to grow to USD 369.19 billion by the end of 2037 from USD 173.09 billion in 2024, exhibiting a CAGR of around 6%. By the end of 2025, biofuels industry is assessed at USD 180.36 billion. The U.S. accounts for the highest production capacity of 55%, followed by Brazil (27%), the EU (5%), China (3%), India (3%), Canada (2%), Thailand (1%), Argentina (1%), RoW (3%) in 2021.

Second-generation or Mixed Biorefineries in the U.S., in Million Gallons Per Year

Company

State

City

Feedstock

Production Capacity (MGY)

Project LIBERTY

IA

Emmetsburg

Cellulosic Biomass

25

NewEnergyBlue LLC

IA

Mason City

Cellulosic Biomass

20

VERBIO North America Corp.

IA

Nevada

Corn/Cellulosic Biomass

60

Quad County Corn Processors

IA

Galva

Corn/Cellulosic Biomass

38

Ace Ethanol LLC

WI

Stanley

Corn/Cellulosic Biomass

54

POET Biorefning-Iowa Falls LLC

IA

Iowa Falls

Corn/Cellulosic Biomass

115

Louis Dreyfus Grand Junction LLC

IA

Grand

Corn/Cellulosic Biomass

125

POET Biorefning-Shell Rock LLC

IA

Shell Rock

Corn/Cellulosic Biomass

140

PureField Ingredients LLC

KS

Russell

Corn/Sorghum/Cellul. Biomass

55

Pelican Acquisition LLC

CA

Stockton

Corn/Sorghum/Cellul. Biomass

60

ELEMENT LLC

KS

Colwich

Corn/Sorghum/Cellul. Biomass

70

Source: USDA


Second-Generation Biofuels Market trends
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Second-Generation Biofuels Market: Growth Drivers and Challenges

Growth Drivers

  • Favorable Government Tax credits: A second-generation biofuel manufacturer, registered with the Internal Revenue Service (IRS) are eligible for a tax credit up to USD 1.01 per gallon of 2G biofuel that is: used and sold as a fuel by a business in a trade; used and sold by the purchaser in develop a second-generation biofuel mixture; retailed as a vehicle fuel. Additionally, alcohol fuel tax credits are eligible for second generation biofuel, and the credit amount is USD 0.46 per gallon for ethanol and USD 0.41 per gallon non non-ethanol biofuels.Second-generation biofuels are typically sourced from hemicellulosic or lignocellulosic biomass or cyanobacteria, cultivated algae, or lemna. To qualify, it needs to comply with the U.S. Environmental Protection Agency (EPA) and its additive registration requirements. Alcohol with a proof of less than 150, fuel that has a water or sediment content exceeding 4%, and fuel with an ash content greater than 1% are not classified as second-generation biofuels. The incentive can be utilized as a credit against the producer's income tax liability. According to current law, only qualified fuel produced in the United States for consumption within the United States is eligible for this incentive.

 

  • High yield of Jatropha oil for biodiesel: As of 2024, Jatropha plantations were widespread across Egypt.  Jatropha propagates easily, has high drought tolerance, and has comparatively 30-50% more oil content than other oil crops. The cultivated area of Jatropha is approximately 900,000 ha globally, 120,000 ha in Africa, 760,000 ha in Asia, and around 20,000 ha in Latin America. All desert areas in New Valley and Upper Egypt governorates are considered potential areas for Jatropha plantations. Such marginal Jatropha land in Egypt covers 844 ha. The pretreatment of Jatropha seeds improves oil extraction by 24% of the internal energy of solvent extraction and 66% for mechanical extraction. Moreover, screw press type in mechanical extraction which yields an extraction of 65-90% by weight, resulting in oil output efficiency of 96%.Italy and the U.S. also observed a prominent rise in Jatropha output owing to new supportive laws. In Asia, Indonesia, Singapore, Malaysia, and China, as well as in Latin America, Argentina, and Brazil, biofuel production from Jatropha is rising exponentially. was quickly rising. Indonesia’s biodiesel generation is estimated to expand at a rate of 23% by the end of 2030, whereas biodiesel usage is projected to grow by 7% in the next decade.
  • Rampant rise in electricity consumption: The worldwide electricity demand increased by 4.3% in 2024 and is anticipated to continue to grow at 4% in 2027. In the next three years, the electricity consumption will reach 3,500 TWh. Majority of the additional demand is ascribed to the emerging economies, contributing 85% of the growth. According to the EIA, significant demand came from China in 2024 and registered a CAGR of 4% the same year and is set to garner a 6% rate in 2027. The share of electricity in final energy consumption in China is 28%, which is significantly higher than the U.S. (22%) and the EU (21%).In 2024, 0.9 GW dispatchable capacity was commissioned, of which 0.4 GW was using natural gas and 0.3 GW was classified as a grid stabilization oil-based plant, while the remaining comprised biomass, process heat, and waste. As per the result of the first long-term EIA’s decarbonized power supply auction in April 2024, decarbonized power sources of 4 GW were awarded, which included 0.2 GW for biomass power, 1.1 GW in battery storage, 0.6 GW for pumped storage hydropower, 0.06 GW in hydrogen co-firing, 1.3 GW in nuclear power, and 0.8 GW in ammonia co-firing capacity.In addition, supply capacity reserved in the capacity market has been delivered since April 2024, which is expected to enhance market stability. The Ministry of Energy and Mineral Resources (MEMR) Decree Regulation 11/2024 has extended these changes to include other types of renewable energy, such as wind and biomass. It also establishes a lower local content requirement of 15% for wind projects. In 2024, renewable energy contributed 16% of power generation, with bioenergy being the leading source, accounting for more than 50% of the total. Additionally, variable renewable energy (VRE) constituted 27% of the generation mix.

Net generation for all sectors (thousand megawatthours) in 2024

Second-gen biofuels

September

October

November

December

Wood & wood-derived fuels

2,608

2,297

2,555

2,794

Others

1,230

1,235

1,202

1,230

Total

3,838

3,532

3,756

3,979

Source: EIA

Challenges

  • Lack of availability of feedstocks: One important aspect that could slow the second-generation biofuels market's expansion is the scarcity of feedstocks. The majority of second-generation biofuels are made from non-food feedstocks, including agricultural and forestry waste, which may be in short supply or in just certain seasons. The main cause of the limited availability of feedstocks is the potentially expensive and ineffective collection and transportation of biomass.  For instance, the need to gather agricultural waste from various sources and bring it to a central location for processing could significantly increase the price of producing biofuels. Additionally, elements including weather patterns and changes in land use could have an impact on the quantity and quality of biomass, which could have an impact on the supply of feedstocks.

Base Year

2024

Forecast Year

2025-2037

CAGR

26.3%

Base Year Market Size (2024)

USD 11.52 billion

Forecast Year Market Size (2037)

USD 239.72 billion

Regional Scope

  • North America (U.S., and Canada)
  • Asia Pacific (Japan, China, India, Indonesia, Malaysia, Australia, South Korea, Rest of Asia Pacific)
  • Europe (UK, Germany, France, Italy, Spain, Russia, NORDIC, Rest of Europe)
  • Latin America (Mexico, Argentina, Brazil, Rest of Latin America)
  • Middle East and Africa (Israel, GCC North Africa, South Africa, Rest of the Middle East and Africa)

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Second-Generation Biofuels Segmentation

Application (Transportation, Power Generation)

The transportation segment in second-generation biofuels market is anticipated to garner the highest revenue by the end of 2037. The growth of the segment can be attributed to growing urbanization. Approximately 4.4 billion people, or 56% of the world's population, reside in urban areas. By 2050, approximately 7 out of 10 people will live in cities, with the urban population predicted to more than double its current size. The demand for transportation grows along with the population of metropolitan areas. The transportation sector contributes significantly to greenhouse gas emissions, and the usage of second-generation biofuels helps reduce these emissions. Since they are produced from renewable energy resources and minimize reliance on non-renewable resources such as oil, biofuels are seen as a more environmentally friendly alternative to fossil fuels.

Process (Biochemical Process, Thermochemical Process)

The thermochemical process segment in second-generation biofuels market is expected to have the highest growth over the forecast period. The manufacturing of second-generation biofuels heavily relies on thermochemical processes. Non-food feedstocks, including forestry and agricultural waste, may be converted into biofuels quite effectively using thermochemical techniques. Second-generation biofuels are produced from a range of non-food feedstocks, unlike first-generation biofuels, which are primarily made from food crops. Moreover, biofuels with a high energy density could be created using thermochemical processes, making them ideal for use in transportation-related applications. Gasification and pyrolysis thermochemical processes produce biofuels with energy densities that are comparable to or even surpass those of fossil fuels.

Our in-depth analysis of the global second-generation biofuels market includes the following segments:

 

 Feedstock

  • Simple Lignocellulose
  • Complex Lignocellulose
  • Syngas
  • Algae

 

Application

  • Transportation
  • Power Generation

 

 

Type

  • Cellulosic Ethanol
  • Biodiesel
  • Bio Butanol
  • Bio DME

 

Process

  • Biochemical Process
  • Thermochemical Process

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Second-Generation Biofuels Industry - Regional Synopsis

North America Market Forecast   

North America second-generation biofuels market is expected to account for the largest revenue share of 30% by 2037, backed by growing food waste and population in the region. In 2023, the federal government rolled out key standards to build a reliable, clean, and affordable electricity sector, including the Clean Electricity Regulations (CER). It offers USD 60 billion to advance electricity system decarbonization under the Clean Economy Plan and offers Clean Economy Investment Tax Credits (ITCs), Furthermore, Canada Infrastructure Bank (CIB) targeted programming and financing supports decarbonization of electricity production, such as the Smart Renewables Electrification Program. The federal government also introduced the Canada Green Buildings Strategy (2024), the Progress Report (2024), the Hydrogen Strategy (2020), the Small Modular Reactors (SMR) Action Plan (2020), and the Progress Update (2022).

The U.S. second-generation biofuels market is driven by the rising share of modern renewable was 10.9% in 2021 and the change in trend between 2000 and 2021 was 101%, whereas the biofuels and waste share was 5.3% of the final consumption in 2022. The overall power end-use growth was 3% higher in 2022 than in 2021. Furthermore, retail electricity sales to the residential end use sector were roughly 4% more in 2022 than the earlier year, while retail sector sales to the commercial end user was up 3% than in 2021. 

2023 Total Electric Industry- Customers

State

Residential

Commercial

Industrial

Transportation

Total

New England

6,579,669

943,130

21,474

6

7,544,279

Middle Atlantic

16,603,564

2,455,311

33,989

21

19,092,885

East North Central

20,833,849

2,547,590

55,099

11

23,436,549

West North Central

9,915,499

1,517,734

131,428

3

11,564,664

South Atlantic

30,090,394

4,000,173

88,038

13

34,178,618

East South Central

8,853,035

1,484,981

24,411

0

10,362,427

West South Central

17,711,160

2,400,621

419,810

6

20,531,597

Mountain

10,725,657

1,502,127

100,935

6

12,328,725

Pacific Contiguous

19,227,491

2,412,748

201,091

19

21,841,349

Pacific Noncontiguous

742,395

116,913

1,974

0

861,282

U.S. Total

141,282,713

19,381,328

1,078,249

85

161,742,375

Source: EIA

APAC Market Statistics

The APAC second-generation biofuels market is projected to garner a prominent revenue share during the anticipated timeline. Lignocellulose is the most abundant biomass on Earth, derived from various sources including crop residues such as rice straw, corn stover, wheat straw, sugar cane bagasse, municipal solid waste, and forestry residues. Statistical estimates indicate that global annual crop residue production reaches approximately 2,445.2 million tons. Notably, China contributes over 1,039.5 million tons of this total, accounting for more than 42.5% of the global figure. Additionally, Bacillus licheniformis, isolated from Himalayan soil, can produce thermostable cellulase, which demonstrates optimal activity at 60 °C. Several thermophilic cellulase-producing bacteria, such as Bacillus velezensis strain MRC 5958 and Geobacillus sp. KP43, have been characterized after being isolated from hot springs. Another strain, isolated from the Yunnan-Tibet hot springs, Clostridium SYSU GA15002T, can utilize cellobiose, cellulose, xylan, and untreated straw powder for bioethanol production.

Current projections estimate that China’s fuel ethanol capacity and consumption will reach 3.9 billion liters. Production is expected to remain slightly below 2022 levels due to less blending in certain areas, high feedstock prices, and limited imports restricted by high tariffs. Fuel ethanol production is forecasted to rise by 96 million liters, driven by a persistent profitability over the past few years. In 2023, biomass-based diesel (BBD) imports increased by 40% compared to 2022, with over 90% of these imports coming from palm oil biodiesel sourced from Indonesia and Malaysia. Additionally, China exports surged due to demand from the EU, as the country overtook Argentina to become the primary exporter of fatty acid methyl ester (FAME) to the EU in the fourth quarter of 2022.

Second-Generation Biofuels Market value
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Companies Dominating the Second-Generation Biofuels Market

    • The second-generation biofuels market players have identified the shift toward renewable alternatives for electricity generation and have capitalized on the opportunity to expand their customer base. More companies are entering the industry and are engaged in strategic activities such as new grid launches, geographical expansions, and mergers and acquisitions. Some of the prominent players include in second-generation biofuels market: 

    • Abengoa S.A.
      • Company Overview
      • Business Strategy
      • Key Product Offerings
      • Financial Performance
      • Key Performance Indicators
      • Risk Analysis
      • Recent Development
      • Regional Presence
      • SWOT Analysis
    • DuPont de Numours, Inc.
    • Novozymes
    • BP p.l.c.
    • POET, LLC.
    • Renewable Energy Group
    • Gevo Inc.
    • Enerkem Inc.
    • Amyris, Inc.
    • Solazyme Inc.

In the News

  • In August 2024, Cepsa, a leading supplier of marine fuel, announced the commissioning of supplying biofuels to Norwegian Cruise Line Holdings at the Port of Barcelona. The company stated that it can supply sustainable fuels to the cruise industry regularly.
  • In March 2024, Terragia Biofuel announced it had raised a USD 6 million seed round led by Energy Impact Partners (EIP) and Engine Ventures. Terragia Biofuel plans to use the funding to commercialize its new technology to convert cellulosic biomass into ethanol and other products, expand its employee headcount, and initiate partnerships with major biofuel producers.

Author Credits:   Dhruv Bhatia


  • Report ID: 4879
  • Published Date: Apr 08, 2025
  • Report Format: PDF, PPT

Frequently Asked Questions (FAQ)

In the year 2025, the industry size of second-generation biofuels is estimated at USD 16.88 billion.

The second-generation biofuels market size was over USD 11.52 billion in 2024 and is anticipated to cross USD 239.72 billion by 2037, witnessing more than 26.3% CAGR during the forecast period i.e., between 2025-2037. The market growth is driven by growing demand for vehicles, rise in generation of electricity, surge in government initiatives to use biofuels, and others.

North America industry is expected to account for largest revenue share of 30% by 2037, backed by growing food waste, along with growing population in the region.

The major players in the market are Abengoa S.A., DuPont de Numours, Inc., Novozymes, BP p.l.c., POET, LLC., Renewable Energy Group, Gevo Inc., Enerkem Inc., Amyris, Inc., Solazyme Inc.
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